Gem install can throw a ssl exception. This is a solution on Stackoverflow
Summary of the remedy:
1. Download
https://raw.githubusercontent.com/rubygems/rubygems/master/lib/rubygems/ssl_certs/AddTrustExternalCARoot-2048.pem
2. Find out installation location
C:\>gem which rubygems
C:/Ruby21/lib/ruby/2.1.0/rubygems.rb
3. Install the file
Then just copy the .pem file into ../2.1.0/rubygems/ssl_certs/